Development of biomimetic catalytic oxidation methods and non-salt methods using transition metal-based acid and base ambiphilic catalysts
نویسنده
چکیده
This review focuses on the development of ruthenium and flavin catalysts for environmentally benign oxidation reactions based on mimicking the functions of cytochrome P-450 and flavoenzymes, and low valent transition-metal catalysts that replace conventional acids and bases. Several new concepts and new types of catalytic reactions based on these concepts are described. (Communicated by Ryoji Noyori, M.J.A.).
منابع مشابه
Biomimetic oxidation in organic synthesis using transition metal catalysts
Simulation of the function of hepatic flavoenzyme and Cytochrome P-450 with transition metal-complex catalysts results in finding biomimetic, catalytic oxidations of amines, amides, alkenes, and hydrocarbons.
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